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  • 化學與環境工程學院何傳新教授在《Advanced Energy Materials》上發表論文

    發布時間:2019-07-12

    近日,深圳大學化學與環境工程學院何傳新課題組在能源催化方面取得重要進展,研究成果以“General Synthesis of Ultrathin Metal Borate Nanomeshes Enabled by 3D Bark-Like N-Doped Carbon for Electrocatalysis”為題發表在化學材料領域頂級雜志Advanced Energy Materials(JCR一區,影響因子24.884),并被選為封面論文。深圳大學何傳新教授為通訊作者,深圳大學為唯一通訊單位。

    在過去的十年,構建二維過渡金屬納米片已經成為制備高效電催化材料的有效手段。尤其是僅有原子厚度的超薄納米片具備較大的比表面積、較高的表面/體積比,使得表面原子達到最大的暴露。因此,超薄的納米片在氧析出反應中普遍具有優異的電催化活性。但是,超薄納米片的橫向質量擴散能力較差,使得其活性難以進一步提高。與之形成鮮明對比的是,超薄的納米網狀材料不僅完美地繼承了超薄納米片的優勢,而且具備規則的多孔結構,可以極大地促進電催化過程中的傳質,從而提高納米片狀材料的電催化活性。但是,大多數的過渡金屬納米網都是使用硬模板的方法合成,具有合成過程繁瑣的缺點。因此,開發簡單、有效的方法來合成超薄的過渡金屬納米網并進一步研究其在電催化反應中的獨特優勢,是十分有意義的。最近,深圳大學化學與環境工程學院何傳新教授課題組介紹了一種利用三維樹皮狀氮摻雜碳為納米反應器來合成超薄金屬硼酸鹽納米網的通用方法,并將所制備的金屬納米網用于完全電解水,研究了超薄納米片組成的網絡結構在電催化反應中的獨特優勢。

     

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